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Improving the tribological properties of Stainless Steels by low-temperature surface hardening
(2022)
Ferromagnetism is of increasing importance in the growing field of electromobility and data storage. In stable austenitic steels, the occurrence of ferromagnetism is not expected and would also interfere with many applications. However, ferromagnetism in austenitic stainless steels after low-temperature nitriding has already been shown in the past. Herein, the presence of ferromagnetism in austenitic steels is discovered after low-temperature carburization (Kolsterizing), which represents a novel and unique finding. A zone of expanded austenite is established on various austenitic stainless steels by low-temperature carburization and the respective ferromagnetism is investigated in relation to the alloy composition. The ferromagnetism occurring is determined by means of a commercial magnetoinductive sensor (Feritscope). Ferromagnetic domains are visualized by magnetic force microscopy and a ferrofluid. X-ray diffraction measurements indicate a clear difference in the lattice expansion of the different alloys. Furthermore, a different appearance of the magnetizable microstructure regions (magnetic domain structure) is detected depending on the grain orientation determined by electron backscatter diffraction (EBSD). Strongly pronounced magnetic domains show no linear lattice defects, whereas in small magnetizable areas linear lattice defects are detected by electron channeling contrast imaging and EBSD.
This paper presents the current state of development and selected technological challenges in the application of ecologically and economically sustainable nets for aquaculture based on ongoing development projects. These aim at the development of a new material system of high-strength stainless steel wires as net material with environmentally compatible antifouling properties for nearshore and offshore aquacultures. Current plastic netting materials will be replaced with high-strength stainless steel to provide a more environmentally friendly system that can withstand more severe mechanical stresses (waves, storms, tides and predators). A new antifouling strategy is expected to solve current challenges, such as ecological damage (e.g., due to pollution from copper-containing antifouling substances or microplastics), high maintenance costs (e.g., cleaning and repairs), and shorter service life. Approaches for the next development steps are presented based on previous experience as well as calculation models based on this experience.
Low temperature carburizing of a series of austenitic stainless with various combinations of chromium and nickel equivalents was performed. The investigation of the response towards low temperature carburized for three stainless steels with various Cr- and Ni-equivalents showed that the carbon uptake depends significantly on the chemical composition of the base material. The higher carbon content in the expanded austenite layer of specimen 6 (1.4565) and specimen 4 (1.4539/AISI 904L) compared to specimen 2 (1.4404/AISI 316L) is assumed to be mainly related to the difference in the specimens’ chromium content. More chromium leads to more lattice expansion. Along with the higher carbon content, higher hardness values and higher compressive residual stresses in the expanded austenite zone are introduced than for low temperature carburized AISI 316L. The residual stresses obtained from X-ray diffraction lattice strain investigation depend strongly on the chosen X-ray elastic constants. Presently, no values are known for carbon (or nitrogen) stabilized expanded austenite. Nevertheless, first principle elastic constants for γ′&minus Fe4C appear to provide realistic residual stress values. Magnetic force microscopy and measurement with an eddy current probe indicate that austenitic stainless steels can become ferromagnetic upon carburizing, similar for low temperature nitriding. The apparent transition from para- to ferromagnetism cannot be attributed entirely to the interstitially dissolved carbon content in the formed expanded austenite layer but appears to depend also on the metallic composition of the alloy, in particular the Ni content.
Thermochemical surface hardening is used to overcome the weak mechanical performance of austenitic and duplex stainless steels. Both low-temperature carburizing and nitrocarburizing can improve the hardness, wear, galling, and cavitation resistance, while maintaining their good corrosion resistance. Therefore, it is crucial to not form chromium-rich precipitates during hardening as these can deteriorate the passivity of the alloy. The hardening parameters, the chemical composition of the steel, and the manufacturing route of a component determine whether precipitates are formed. This article gives an overview of suitable alloys for low-temperature surface hardening and the performance under corrosive loading.
The project aims for the development of a new material system from high tensile stainless steel wires as net material with environmentally compatible antifouling properties for off-shore fish farm cages. Therefore, current net materials from textiles (polyamide) shall be partially replaced by high strength stainless steel in order to have a more environmentally compatible system which meets the more severe mechanical loads (waves, storms, predators (sharks)). With a new antifouling strategy current issues like reduced ecological damage (e.g. due to copper disposal), lower maintenance costs (e.g. cleaning) and reduced durability shall be resolved.
Martensitic stainless steels has a wide use, for example for blades, knifes or cutter. The best corrosion resistance of these materials is in hardened condition. For better mechanical properties a tempering is normally applied to increase the durability. The tempering is also reducing the hardness and finally the corrosion resistance. Austempering is meanly used at low alloyed steels and brings a good compromise between durability, hardness and corrosion resistance. For martensitic stainless steels, austempering is normally not a topic because of the very long tempering times.
This work shows first results of austempering of some standard martensitic stainless steels and the influence to corrosion resistance. For reference, hardened and also hardened and tempered specimens were investigated. The corrosions resistance was investigated by electrochemical methods.